First of all - what are you actually trying to do? A customer from Canada for your UK subsidiary needs a UK export code by default unless you fulfill from a local Canadian entity/warehouse e.g. If you use legacy tax it is sadly quite limited what you can do, suitetax e.g. allows for more tax registrations per customer/sub. If you need a specific tax code with a specific behaviour or booking you can always create a new tax type with codes and control accounts - but note that you have to sort the reporting manually then.