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Anyone know where the template is for the email that gets send from Invoices when “TO BE EMAILED” is ticked?

This cannot be modified. The body of the email sent via the standard To Be Emailed checkbox with the “Adobe Acrobat” in it is not customizable.

I may be misunderstanding, but there's a Email Message Template setting on form setup. I don't believe you can change the default email template to Tucker's point, but you can whip up a basic email template pretty quickly and set that as the default.

Maybe this setting doesn't apply to the "To Be Emailed" box though, I'm not sure.  I generally don't use that because I'm too paranoid about emails firing off automatically.

If it's not the Default Email Template set there, you should be able to drop Page: Email Templates into Global Search to get to the page with your email templates and modify the one that's set.

That’s not related to the To Be Emailed box.