In the record (Join field) you select Vendor and then in the field you can select comments (it may be called note, description or memo also)
Lastly, it may not be possible using the joined record because NS will validate the field type. The Comments field is a long text type and the memo is a free text type so they may not be compatible. But you might try a formula. In the formula of your WF try {vendor.comments}, {vendor.note} or {vendor.description}. See if one of those works