Create a new field called "Last Approved Amount" on the PO.
Use a set field value action upon entry into the approved state to set this field to the {total} field from the PO
Add a transaition to the Approved state with the criteria of Last Approved Amount is NOT EQUAL to {total}
Transition after record submit
Transition to the pending approval state (or a new pending approval state called PO AMOUNT CHANGED)