You can design an advanced PDF(template), to print out a Vendor Bill.
However, it is not possible(through standard NS-feature), to render the record(VB) data, to a printing template.
This means, no matter how you decide to build/shape the print template, you will need a scripted solution, to render the record(as a custom dataset), to the desired print template(...which can be an advanced PDF one).
I think, you could have a VB, though, in an email(html template).